Photoredox & Electrochemical Reactions
Photoredox and electrochemical methodologies revolutionize synthesis by using controlled redox events to generate reactive intermediates under mild, sustainable conditions. Visible-light photocatalysis enables selective radical formation, facilitating complex bond constructions without conventional high-energy reagents. Electrochemical synthesis replaces stoichiometric oxidants and reductants with electricity, allowing precise control over electron transfer and minimizing waste generation. Hybrid photoelectrochemical strategies combine illumination and electrochemical potential to unlock new pathways with exceptional selectivity. Advances in catalyst design, semiconductor materials, and flow-electrochemical systems further enhance scalability and efficiency. These reaction platforms offer powerful tools for accessing diverse functional groups, activating inert bonds, and enabling late-stage functionalization in pharmaceuticals and materials science while aligning synthetic chemistry with green-energy principles.
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